Chloride stress corrosion cracking in austenitic stainless steel. I find that much of the material is either wrong, terribly confusing, or else completely misses the point. Chlorideassisted stresscorrosion cracking in type 316. Effect of halogens and inhibitors on the external stress. Seawater contains a complex mixture of salts which wet at various rh, e.
Stress corrosion cracking in the necessary condition is to have tensile strength. This recapitulation of experiences with stresscorrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. Avoiding stress corrosion cracking of carbon low alloy and austenitic stainless steels in chloride and caustic environments synopsis this maintenance best practice guide is concerned with the performance of carbon and low alloy steels, and austenitic stainless steels, in chloride and caustic containing fluids. Scc is known as an insidious form of corrosion failure and it results in a significant drop in the mechanical strength only with little metal loss. This type of failure is referred to as stress corrosion cracking scc. Whenever stainless steel is exposed to chloride concentrations and stress levels, chloride stress corrosion cracking cscc can occur. Structural failure due to scc can be very unpredictablefailure could occur after as little as a few hours of exposure, or the equipment could continue to function normally for. The weldments in these canisters involving segregated and sensitized zones along with residual stress are exposed to coastal environments including salty air. Stress corrosion cracking stress corrosion cracking scc is a known condition, which can sometimes occur when certain conditions are met and occurring simultaneously. Allowable chlorides in cooling tower circulating water.
The following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. Based on this failure analysis, geothermal or other buried heated water systems must consider. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Temperature is a significant environmental factor affecting cracking. Primary water stress corrosion cracking pwscc of inconel 600 addressees. Chloride stress corrosion cracking inspectioneering. Stress corrosion cracking scc of nickelbased alloys.
Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Chlorines effect on corrosion in drinking water systems by michelle moore ndwc promotions writereditor. Singh raman 1, and wai hoong siew 2 1 department of mechanical and aerospace engineering, monash university, melbourne, victoria 3800, australia 2 mechanical engineer, ibm australia 60 city road melbourne, victoria 3006 australia. All holders of operating licenses or construction permits for pressurized. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. A pwscc mechanism based on an ordering reaction in alloy 600 is proposed. C steel boilers are also susceptible to a form of stress corrosion cracking scc termed caustic cracking. Stress corrosion cracking scc can slowly destroy your brewery equipment without warning. There are, consequently, a number of approaches that we can use to prevent scc, or at least to give an acceptable lifetime. There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc. Stress corrosion cracking international institute of. Small drinking water treatment systems face a dilemma.
I am still skeptical on the viability of using 340l or 316 ss pipe in this situation due possibility of the establishment of an interface and potential for stress corrosion and then the cracking due to the cl levels and temperature. Boiling water reactors bwrs operate with very high purity water. Environmental protection agency epa, the lead and copper rule and the ground water rule, seem to work against each other, even though each rule is meant to benefit the public. Fundamentals of metallic corrosion in fresh water by j. There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2sinduced scc. This paper shows the experience of failure of a heat exchanger due to chloride stress corrosion cracking scc.
Alloy 600 also performs well at cryogenic temperatures. C are not recommended for 304 or 316 as they are at risk of sudden failure from chloride stress corrosion cracking. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. This study is to identify factors responsible for loss of production due to problems in plant and equipment. Stress corrosion cracking scc results from the combined action of three factors. Overview of stress corrosion cracking scc in water systems. The ordering reaction in alloy 600 is an indispensable process during reactor operating conditions. Guidelines for using stainless steel in the water and desalination. Primary water stress corrosion cracking pwscc of inconel 600 united states nuclear regulatory commission office of nuclear reactor regulation washington, d. Jun 09, 2014 avoiding stress corrosion cracking of carbon low alloy and austenitic stainless steels in chloride and caustic environments synopsis this maintenance best practice guide is concerned with the performance of carbon and low alloy steels, and austenitic stainless steels, in chloride and caustic containing fluids. Stress corrosion cracking scc stress corrosion cracking is to bear the stress of the alloy in the corrosive environment because of strong expansion of the alternate failure pattern of a generic term. Stress corrosion cracking of austenitic stainless steels in chloride.
The residual stresses from the welded brackets, supports and nozzles and the hot humid environment combined with the chloride levels of the insulation provided the necessary conditions for chloride induced stress corrosion cracking to occur. Carbon steel and type 304 stainless steel samples were exposed in thirteen corrosion tests conducted in solutions with varying ph, oxygen content, so2 content and chloride ion content in a simulated sour water solution produced in the laboratory. Rr298 chloride stress corrosion cracking of duplex stainless. Stress corrosion cracking scc is produced by the simultaneous interaction of three essential factors. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. An engineering approach to stresscorrosion cracking of austenitic stain less steelhow it can. Stress corrosion cracking scc in boilers and cooling. This form of corrosion is controlled by maintaining low chloride ion and oxygen content in the environment and use of lowcarbon steels. This can occur even when the bulk concentration of caustic is below the danger level because of a variety of processes that can lead to localized accumulations of caustic well in excess of average concentrations. Primary water stress corrosion cracking pwscc mechanism. Chloride stress corrosion cracking is a well known form of scc, typically caused by. First, the part must be stressed, either from an applied force or due to residual stress usually from forming. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion.
The combination of tensile stress and a specific corrosive environment can crack stainless steels. Carbon steel and type 304 stainless steel samples were exposed in thirteen corrosion tests conducted in solutions with varying ph, oxygen content, so 2 content and chloride ion content in a simulated sour water solution produced in the laboratory. Transgranular stress corrosion cracking of 304l stainless. Chloride induced stress corrosion cracking of type 304 and. Corrosionpedia what is stress corrosion cracking scc. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. Chlorines effect on corrosion in drinking water systems. This recapitulation of experiences with stress corrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. Corrosion resistance tables nominate a chloride level of approx. This type of failure is known as stress corrosion cracking, often abbreviated to scc. Recommendations for assessing susceptibility to clscc 7. Stress corrosion cracking of steel in liquefied ammonia. Assessing the risk of underdeposit chlorideinduced stress. Your tanks are the core of your brewery, so it is important to understand what scc is, what causes it, and what to do when your tanks suffer from this type of damage.
Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of. Rossum in preparation for this paper, ive examined some of the available literature on water well corrosion. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Stress corrosion cracking of brittle fracture surface, but it may also occur in high toughness materials. Ctlchloride induced stress corrosion cracking of stainless. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Stress corrosion cracking of an austenitic stainless steel in. The absence of o2 is somewhat of a problem to me both for the ss and the variety of bugs.
Methods of minimizing chloride stress corrosion cracking. Avoiding stress corrosion cracking of carbon low alloy and. Chlorine and chloride are different forms of the same element but with vastly different effects on stainless steel. Stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Chloride stress corrosion cracking of an austenitic stainless steel. An investigation of the chloride effect on stress corrosion cracking, corrosion, vol.
Stress corrosin cracking scc of duplex stainless steel 5. Chloride comes from a variety of sources including various feeds from upstream units, overhead washwater systems, and carry over by recycled hydrogen gas. Prevention of external chloride stress corrosion cracking of. Likely sources of soluble chloride are water penetrating the cladding or from a small stream leak in the vessel. Chloride induced stress corrosion cracking ciscc of spent nuclear fuel storage canisters is a serious concern since it can potentially lead unexpected premature failure of the canisters. In addition design condition such as stress concentration devices and inappropriate commissioning procedures can make the austenitic steel tubes prone to fail too early. Prevention of external chloride stress corrosion cracking. The methodology of the drip procedure of the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to the insulation industry. Stress corrosion cracking of an austenitic stainless steel in nitritecontaining chloride solutions r. Chloride stress corrosion cracking although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless steels varies substantially. Addition of nitrite to the chloride solution, which is reported to have inhibitive influence on corrosion of stainless. Four factors, are required before stress corrosion cracking can occur. Stress corrosion cracking in a brewery paul mueller company.
A corrosive medium especially chloridebearing or hydrogensulphide h 2s media. Corrosion rates were calculated, and ubends were examined for stresscorrosion cracking. Chloride stress corrosion cracking scc is about as well known as any scc mechanism can be, so i wont dwell much on it here, but want to mention it for the sake of completeness and hopefully mention something that is not as commonly known about it. While it is rare, formed parts can develop fractures after they are placed in service. Chloride stress corrosion cracking in bfw preheater in. If stress corrosion cracking is occurring in the craft brewery, it is most likely due to soluble chloride coming from the insulation. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. Pdf chloride induced stress corrosion cracking of type 304 and. Chloride induced stress corrosion cracking of stainless.
Measures to control susceptibility to transgranular stress corrosion cracking tgscc of austenitic stainless steels include reducing the temperatures and lowering chloride concentration by using a higher purity makeup water source for the cooling water. This demonstrates an essential feature of localised corrosion on. Chlorideinduced stress corrosion cracking in aqueous environments. Stress corrosion cracking scc is cracking due to a process involving conjoint corrosion and straining of a metal due to residual or applied stresses. Stress corrosion cracking scc is a progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment. Chloride stress corrosion cracking in austenitic stainless. Branched, brittle cracks were observed in the failure region and exhibited transgranular propagation. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and incurs plant downtime. To evaluate chlorideinduced stress corrosion cracking of type 304 stainless steel, corrosion 2012, march 1115, 2012, salt lake city, ut, agencywide documents access and management system adams accession no. Inherent stress arising from the manufacturing process or induced stress arising from incorrect installation.
An activation energy for the ordering reaction in alloy 600, q. Stress corrosion cracking of an austenitic stainless steel. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Cooling tower suppliers nominate an allowable chloride level of approx. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds ap. May 29, 2016 c steel boilers are also susceptible to a form of stress corrosion cracking scc termed caustic cracking. In these cases, the pipework is usually covered with. Based on the temperature, available moisture, stress level, and type of material used it was determined that the likely cause of failure was neutral ph, dilute chlorideinduced stress corrosion cracking. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. While no stainless steel can be completely immune, swageloks alloy 316 stainless steel fittings have performed exceptionally well in testing. Chlorides simulating sea salt particles were put on the gage section of the ss as droplets of synthetic sea water. Controlling stress corrosion cracking scc in order for scc to occur, we require a susceptible material, an environment that will cause cracking of that material and a high enough stress or stress intensity factor. Pitting corrosion of a stainless steel is illustrated in the figure 1.
Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Alloy 825 is more resistant to stress corrosion cracking in chloride solutions. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. Stress corrosion cracking scc in boilers and cooling water. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Higher temperatures reduce the permissible chloride level. Pdf stress corrosion cracking scc of nickelbased alloys.
This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride solution. Chloride stress corrosion cracking in austenitic stainless steel 6. The alloy also displays very good levels of resistance to chloride stresscorrosion cracking, ammonia, pitting in fresh and salt water, exhaust gasses and most organic acids and compounds. Technical basis for water chemistry control of igscc in boiling.
The actual pitting corrosion phenomenon is shown on propeller shaft of high speed craft, and the pit depth was measured with dial. Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to cscc. Power systemswater reactors, traverse city, mi, august 1987, published in. The standard 304304l and 316316l grades are most susceptible. High residual or applied stress, temperature above 6571c 150160f and chlorides increase the likelihood of cscc. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Mechanical engineer, ibm australia, 60 city road, melbourne, victoria. Or a structure under static tensile stress, much below the yield stress, in contact with corrosive environment may fail due to scc. Austenitic stainless steel may be susceptible to chloride stress corrosion cracking cscc. Corrosion rates were calculated, and ubends were examined for stress corrosion cracking. Introduction the following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin.